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Iota carrageenan sigma6/21/2023 Wang Qiujun, Fan Huanhuan, Fan Li-Zhen, Shi Qjao (2013) Preparation and performance of a non-ionic plastic crystal electrolyte with the addition of polymer for lithium ion batteries. Taib NU, Idris NH (2014) Plastic crystal-solid biopolymer electrolytes for rechargeable lithium batteries. Polym Testing 58:116–125Ĭhandra Sekhar P, Naveen Kumar P, Sharma AK (2012) Effect of plasticizer on conductivity and cell parameters of (PMMA + NaClO 4) polymer electrolyte system. Muchakayala Ravi, Song Shenhua, Gao Shang, Wang Xiaoling, Fan Youhua (2017) Structure and ion transport in an ethylene carbonate-modified biodegradable gel polymer electrolyte. Monisha S, Mathavan T, Selvasekarapandian S, Milton Franklin Benial A, Prema latha M (2016) Preparation and characterization of cellulose acetate and lithium nitrate for advanced electrochemical devices. J Phys Chem B 120(44):11567–11573Īmran NNA, Manan NSA, Kadir MFZ (2016) The effect of LiCF3SO3 on the complexation with potato starch-chitosan blend polymer electrolytes. Ramlli MA, Isa MIN (2016) Structural and ionic transport properties of protonic conducting solid biopolymer electrolytes based on carboxymethyl cellulose doped ammonium fluoride. Rajeswari N, Selvasekarapandian S, Karthikeyan S, Prabu M, Hirankumar G, Nithya H, Sanjeeviraja C (2011) Conductivity and dielectric properties of polyvinyl alcohol-polyvinylpyrrolidone poly blend film using non-aqueous medium. Mobarak NN, Jumaah FN, Ghani MA, Abdullah MP, Ahmad A (2015) Carboxymethyl carrageenan based biopolymer electrolytes. Pereira L, Gheda SF, Ribeiro-Claro PJA (2013) Analysis by vibrational spectroscopy of seaweed polysaccharides with potential use in food, pharmaceutical, and cosmetic industries. Tuvikenea Rando, Truusa Kalle, Vaherb Merike, Kailasb Tiiu, Martinc Georg, Kersenc Priit (2006) Extraction and quantification of hybrid carrageenans from the biomass of the red algae Furcellaria lumbricalis and Coccotylus truncates. Mahmood Wan Ahmad Kamil, Khan Mohammad Mizanur Rahman, Yee Teow Cheng (2014) Effects of reaction temperature on the synthesis and thermal properties of carrageenan ester. Kimura K, Hassoun J, Panero S, Scrosati B, Tominaga Y (2015) Electrochemical properties of a poly(ethylene carbonate)-LiTFSI electrolyte containing a pyrrolidinium-based ionic liquid. Rani Mohd Saiful Asmal, Rudhziah Siti, Ahmad Azizan, Mohamed Nor Sabirin (2014) Biopolymer electrolyte based on derivatives of cellulose from kenaf bast fiber. Ionics 22(6):841–851Īlves R, Donoso JP, Magon CJ, Silva IDA, Pawlicka A, Silva MM (2016) Solid polymer electrolytes based on chitosan and europium triflate. Shamsudin IJ, Ahmad A, Hassan NH, Kaddami H (2016) Biopolymer electrolytes based on carboxymethyl-carrageenan and imidazolium ionic liquid. These results recommend the suitability of the fabricated polymer electrolyte for lithium ion battery system. Linear sweep voltammetry shows that the highest conducting sample is electrochemically stable up to 2.36 V without SN, and it is 3.1 V with SN addition. Transport parameters of diffusion coefficients and mobility of cations and anions are also in tune with the conductivity results. Transference number analysis also reveals that the cause of conductivity is primarily due to ions with the highest ionic transference number of 0.92 (Wagner’s method) and cationic transference number of 0.58 (Bruce and Vincent method) for the highest conducting plasticized sample. The inclusion of 0.3 wt% of SN into this polymeric system has improved the value of ionic conductivity to 3.33 × 10 −3 S cm −1 at ambient temperature, and the activation energy is found to be very low for this concentration. The highest ionic conductivity at room temperature is 3.57 × 10 −4 S cm −1 for the film composition of 1.0 g i-carrageenan/0.5 wt% LiClO 4. The obtained biopolymer electrolytes are characterized by X-ray diffraction, Fourier-transform infrared, differential scanning calorimetry and AC impedance studies. Succinonitrile (SN) plastic crystal has been used as an additive to optimize the conductivity of i-carrageenan biopolymer electrolytes. A non-toxic and bio-active natural polymer electrolyte iota-carrageenan (i-carrageenan) with LiClO 4 has been prepared by conventional solution casting technique.
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